Published in
Royal Society of Chemistry, Chemical Science, 20(11), p. 5328-5332, 2020
DOI: 10.1039/c9sc05982b
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Regio- and diastereoselective reactions of chiral secondary alkylcopper reagents with propargylic phosphates: preparation of chiral allenes
Journal article published in 2020 by
Juri Skotnitzki,
Alexander Kremsmair,
Daniel Keefer 
,
Franziska Schüppel,
Brieuc Le Cacher de Bonneville,
Regina de Vivie-Riedle ,
Paul Knochel
,
Franziska Schüppel,
Brieuc Le Cacher de Bonneville,
Regina de Vivie-Riedle ,
Paul Knochel
This paper is made freely available by the publisher.
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Abstract
The diastereoselective SN2′-substitution of secondary alkylcopper reagents with propargylic phosphates enables the preparation of stereodefined alkylallenes.