The microscopic arrangement of different minerals in ores is of high interest for mine planning, mineral processing and extractive metallurgy. Many economically important, naturally occurring minerals are highly absorbing semiconductors. To characterize these materials, we have implemented pump-probe laser scanning microscopy (LSM) in a two-lens reflective configuration that offers efficient collection of signal light by using a combination of galvanometer and sample stage scanning. We show that the short-time (∼10 ps) pump-probe response of a material allows us to distinguish economically important sulfide minerals.