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Royal Society of Chemistry, Chemical Science, 29(11), p. 7615-7618, 2020

DOI: 10.1039/d0sc01278e

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SET processes in Lewis acid–base reactions: the tritylation of N-heterocyclic carbenes

Journal article published in 2020 by Zhaowen Dong ORCID, Cristian Pezzato ORCID, Andrzej Sienkiewicz, Rosario Scopelliti, Farzaneh Fadaei-Tirani ORCID, Kay Severin ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Carbenes as single electron donors: the tritylation of N-heterocyclic carbenes proceeds via an initial SET step, giving highly reactive carbene radical cations and the trityl radical.