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Royal Society of Chemistry, Chemical Science, 14(11), p. 3719-3726, 2020

DOI: 10.1039/d0sc00361a

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New reductive rearrangement of N-arylindoles triggered by the Grubbs–Stoltz reagent Et3SiH/KOtBu

Journal article published in 2020 by Andrew J. Smith, Daniela Dimitrova, Jude N. Arokianathar, Krystian Kolodziejczak ORCID, Allan Young, Mark Allison, Darren L. Poole ORCID, Stuart G. Leach, John A. Parkinson ORCID, Tell Tuttle ORCID, John A. Murphy ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

N-Arylindoles are transformed into dihydroacridines in a new type of rearrangement, through heating with triethylsilane and potassium tert-butoxide.