Published in
Royal Society of Chemistry, Chemical Science, 14(11), p. 3719-3726, 2020
DOI: 10.1039/d0sc00361a
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New reductive rearrangement of N-arylindoles triggered by the Grubbs–Stoltz reagent Et3SiH/KOtBu
Journal article published in 2020 by
Andrew J. Smith,
Daniela Dimitrova,
Jude N. Arokianathar,
Krystian Kolodziejczak 
,
Allan Young,
Mark Allison,
Darren L. Poole ,
Stuart G. Leach,
John A. Parkinson ,
Tell Tuttle ,
John A. Murphy
,
Allan Young,
Mark Allison,
Darren L. Poole ,
Stuart G. Leach,
John A. Parkinson ,
Tell Tuttle ,
John A. Murphy
This paper is made freely available by the publisher.
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Abstract
N-Arylindoles are transformed into dihydroacridines in a new type of rearrangement, through heating with triethylsilane and potassium tert-butoxide.