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Royal Society of Chemistry, RSC Advances, 22(10), p. 12735-12746, 2020

DOI: 10.1039/c9ra10549b

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Binuclear and tetranuclear Zn(ii) complexes with thiosemicarbazones: synthesis, X-ray crystal structures, ATP-sensing, DNA-binding, phosphatase activity and theoretical calculations

Journal article published in 2020 by Piyali Adak, Bipinbihari Ghosh, Antonio Bauzá ORCID, Antonio Frontera ORCID, Steven R. Herron, Shyamal Kumar Chattopadhyay ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

A binuclear and a tetranuclear zinc(ii) of pyruvaldehyde thiosemicarbazone show selective sensing of ATP at pH 7.4 (0.01 M HEPES) in CH3CN–H2O (9 : 1) medium. The DNA binding and phosphatase activities of the complexes are also reported.