Since their discovery, Ultraluminous X-ray sources (ULXs) have attracted attention due to their combination of extreme luminosities and extra-nuclear locations. However, they are a fairly rare phenomenon, and attempts to investigate the general properties of the population have been hindered by a relative lack of known sources. Here, we present a large catalogue of ULX candidates including 655 detections of 475 discrete sources, based on the 2XMM Serendipitous Survey. To demonstrate the potential of such a resource, we present some scientific analysis of this population, focusing on the spectral turnover seen, often at ~6 keV, in the highest quality ULX data. We also demonstrate how the recent reflection and Comptonisation interpretations of this feature may be distinguished observationally in the future, specifically using NGC 4517 ULX1, a previously unanalysed source with high quality data, as an example case. ; Comment: 4 pages, accepted for publication in the Astronomische Nachrichten, to appear in the proceedings of the conference "Ultra-Luminous X-ray sources and Middle Weight Black Holes" (Madrid, May 24-26, 2010)