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Published in

American Association for the Advancement of Science, Science, 6481(367), p. 1030-1034, 2020

DOI: 10.1126/science.aax3520

ECS Meeting Abstracts, 3(MA2020-02), p. 546-546, 2020

DOI: 10.1149/ma2020-023546mtgabs

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Kinetic pathways of ionic transport in fast-charging lithium titanate

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Metastable pathways allow high rates In batteries that allow for fast charging and discharging, lithium usually forms a solid solution with the anode so that the only limiting factor is the ionic diffusion. However, for a lithium titanate (Li 4 Ti 5 O 12 ) anode, the lithium ions interact with two phases and the diffusion is slow in both, but it still shows high-rate capabilities. Zhang et al. used electron energy-loss spectroscopy combined with density functional theory calculations to probe the anomalous behavior. They found that a diffuse interface forms between the starting and ending compositions, Li 4 Ti 5 O 12 and Li 7 Ti 5 O 12 , and this is what allows the lithium ions to travel quickly. Science , this issue p. 1030