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Royal Society of Chemistry, Chemical Science, 25(11), p. 6450-6456, 2020

DOI: 10.1039/d0sc00497a

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Strategies for remote enantiocontrol in chiral gold(iii) complexes applied to catalytic enantioselective γ,δ-Diels–Alder reactions

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Chiral square planar gold(iii) complexes are employed as catalysts in asymmetric Diels–Alder reactions. The non-covalent interactions responsible for the enantioselectivity are revealed through multivariate linear regression analysis.