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Royal Society of Chemistry, Chemical Science, 25(11), p. 6442-6449, 2020

DOI: 10.1039/d0sc00422g

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Mechanistic basis for tuning iridium hydride photochemistry from H2 evolution to hydride transfer hydrodechlorination

Journal article published in 2020 by Seth M. Barrett ORCID, Bethany M. Stratakes, Matthew B. Chambers ORCID, Daniel A. Kurtz ORCID, Catherine L. Pitman ORCID, Jillian L. Dempsey ORCID, Alexander J. M. Miller ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The innate H2 evolution photochemistry of an iridium hydride complex is diverted towards photochemical hydrodechlorination of dichloromethane with high selectivity and quantum yield.