Published in
Royal Society of Chemistry, Chemical Science, 8(11), p. 2121-2129, 2020
DOI: 10.1039/c9sc06089h
Links
Tools
Enantioselective oxygenation of exocyclic methylene groups by a manganese porphyrin catalyst with a chiral recognition site
Journal article published in 2020 by
Finn Burg 
,
Stefan Breitenlechner ,
Christian Jandl,
Thorsten Bach
,
Stefan Breitenlechner ,
Christian Jandl,
Thorsten Bach
This paper is made freely available by the publisher.
Full text: Download
Preprint: archiving forbidden
Data provided by 
Abstract
A Mn porphyrin complex with a remote hydrogen bonding motif induces a high enantioselectivity in the oxygenation of 3-alkylquinolones. Compared to an achiral Mn complex, the site-selectivity was completely altered in favour of less reactive methylene groups.