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De Gruyter, Pure and Applied Chemistry, 2(92), p. 355-381, 2019

DOI: 10.1515/pac-2018-0205

IUPAC Standards Online, 2021

DOI: 10.1515/iupac.92.0026

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Nomenclature for boranes and related species (IUPAC Recommendations 2019)

Distributing this paper is prohibited by the publisher
Distributing this paper is prohibited by the publisher

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Abstract

Abstract An appraisal of the current IUPAC recommendations for the nomenclature of boranes and related systems has been undertaken. New developments in the field have been investigated and existing nomenclature systems have been adapted to accommodate these new developments. The principal areas considered are stoichiometric and structural nomenclature (including heteroatom and metal-atom subrogation, as well as substitution of hydrogen), conjoined-cage species, supra-icosahedral systems, and sub-icosahedral non-standard structures. Elements of substitutive, additive, and replacement nomenclature systems have been integrated into individual names to address contentious problems in boron nomenclature that have been around for a long time.