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American Chemical Society, Organometallics, 21(31), p. 7610-7617, 2012

DOI: 10.1021/om300918v

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A silica-supported double-decker silsesquioxane provides a second skin for the selective generation of bipodal surface organometallic complexes

Journal article published in 2012 by Jeff Espinas, Jérémie D. A. Pelletier, Edy Abou-Hamad, Lyndon Emsley, Jean-Marie Basset ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A well-defined silica-based material with a homogeneous nanolayer presenting identical pairs of vicinal silanols has been prepared by reaction of the surface organometallic species[ SiOZr(CH2CMe3)(3)], obtained on a silica dehydroxylated at 900 degrees C, with the double-decker-shaped silsesquioxane (OH)(2)DD(OH)(2). The surface structure has been established using extensive NMR characterization (H-1, C-13, Si-29, HETCOR, double-quantum, triple-quantum). Treatment with Zr(CH2CMe3)(4) leads to the first well-defined single-site bipodal grafted bis-neopentyl zirconium complex.