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CSIRO Publishing, Australian Journal of Chemistry, 1(73), p. 16, 2020

DOI: 10.1071/ch19314

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Assembly of Three Lanthanide Coordination Polymers from 2-(4-Carboxybenzyloxy) Benzoic Acid Ligand: Synthesis, Structure, and Fluorescent Properties

Journal article published in 2020 by Shu-Ju Wang, Yi-Hui Jiang, Han-Lin Wu, Li-Xin You ORCID, Gang Xiong, Fu Ding, Ya-Guang Sun
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Three new coordination polymers, {[Ln(cbb)(Hcbb)(DMF)·H2O]n, Ln=Sm (1), Eu (2), Tb(3), H2cbb=2-(4-carboxybenzyloxy) benzoic acid, DMF=N,N-dimethylformamide}, have been synthesised by a solvothermal reaction and structurally characterised by infrared spectroscopy, elemental analysis, thermogravimetry analysis, and X-ray single-crystal diffraction. The results of single-crystal X-ray diffraction indicate that the coordination polymers 1–3 are isostructural, belong to a triclinic system, space group P-1, and show 1D chain structures through the H2cbb ligands connecting adjacent lanthanide ions. In addition, the fluorescence properties of polymers 1–3 were also investigated.