In this paper, multifrequency synthetic aperture radar (SAR) images from ALOS/PALSAR, ENVISAT/ASAR and Cosmo-SkyMed sensors were studied for forest classification in a test area in Central Italy (San Rossore), where detailed in-situ measurements were available. A preliminary discrimination of the main land cover classes and forest types was carried out by exploiting the synergy among L-, C- and X-bands and different polarizations. SAR data were preliminarily inspected to assess the capabilities of discriminating forest from non-forest and separating broadleaf from coniferous forests. The temporal average backscattering coefficient ( σ ¯ °) was computed for each sensor-polarization pair and labeled on a pixel basis according to the reference map. Several classification methods based on the machine learning framework were applied and validated considering different features, in order to highlight the contribution of bands and polarizations, as well as to assess the classifiers’ performance. The experimental results indicate that the different surface types are best identified by using all bands, followed by joint L- and X-bands. In the former case, the best overall average accuracy (83.1%) is achieved by random forest classification. Finally, the classification maps on class edges are discussed to highlight the misclassification errors.