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Springer, Photochemical & Photobiological Sciences, 9(6), p. 987-994, 2007

DOI: 10.1039/b708414e

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Solvent effects on the charge transfer excited states of 4-dimethylaminobenzonitrile (DMABN) and 4-dimethylamino-3,5-dimethylbenzonitrile (TMABN) studied by time-resolved infrared spectroscopy: A direct observation of hydrogen bonding interactions

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Time-resolved infrared absorption spectra of the C≡N bands of photoexcited TMABN and DMABN have been measured in non-polar hexane, polar aprotic THF and polar protic butanol with high temporal and spectral resolution (