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IOP Publishing, Journal of Physics D: Applied Physics, 22(47), p. 224002

DOI: 10.1088/0022-3727/47/22/224002

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Origin of the energetic ions at the substrate generated during high power pulsed magnetron sputtering of titanium

Journal article published in 2014 by Christian Maszl ORCID, Wolfgang Breilmann, Jan Benedikt ORCID, Achim von Keudell
This paper is available in a repository.
This paper is available in a repository.

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Abstract

HiPIMS plasmas generate energetic metal ions at the substrate as a major difference to conventional direct current magnetron sputtering. The origin of these ions is still an open issue, which is unraveled by using two fast diagnostics: time resolved mass spectrometry with a temporal resolution of 2 $μ$s and phase resolved optical emission spectroscopy with a temporal resolution of 1 $μ$s. A power scan from dcMS-like to HiPIMS plasmas was performed, with a 2-inch magnetron and a titanium target as sputter source and argon as working gas. Clear differences in the transport as well in the energetic properties of Ar$^{+}$, Ar$^{2+}$, Ti$^+$ and Ti$^{2+}$ were observed. For discharges with highest peak power densities a high energetic group of Ti$^+$ and Ti$^{2+}$ could be identified. A cold group of ions is always present. It is found that hot ions are observed only, when the plasma enters the spokes regime, which can be monitored by oscillations in the IV-characteristics in the MHz range that are picked up by the used VI-probes. These oscillations are correlated with the spokes phenomenon and are explained as an amplification of the Hall current inside the spokes as hot ionization zones. To explain the presence of energetic ions, we propose a double layer (DL) confining the hot plasma inside a spoke: if an atom becomes ionized inside the spokes region it is accelerated because of the DL to higher energies whereas its energy remains unchanged if it is ionized outside. In applying this DL model to our measurements the observed phenomena as well as several measurements from other groups can be explained. Only if spokes and a double layer are present the confined particles can gain enough energy to leave the magnetic trap. We conclude from our findings that the spoke phenomenon represents the essence of HiPIMS plasmas, explaining their good performance for material synthesis applications. ; Comment: Intended for Journal of Physics D: Applied Physics, Special issue "Fundamentals of plasma-surface interactions"