Published in
Royal Society of Chemistry, Chemical Science, 45(10), p. 10516-10523, 2019
DOI: 10.1039/c9sc04289j
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Merging hypervalent iodine and sulfoximine chemistry: a new electrophilic trifluoromethylation reagent
Journal article published in 2019 by
Jorna Kalim 
,
Thibaut Duhail,
Thanh-Nghi Le,
Nicolas Vanthuyne,
Elsa Anselmi ,
Antonio Togni ,
Emmanuel Magnier
,
Thibaut Duhail,
Thanh-Nghi Le,
Nicolas Vanthuyne,
Elsa Anselmi ,
Antonio Togni ,
Emmanuel Magnier
This paper is made freely available by the publisher.
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Abstract
Two prominent trifluoromethylation reagent classes join forces in a bench stable hypervalent iodosulfoximine CF3 transfer agent. We report its synthesis, properties and reactivity, opening up new possibilities in trifluoromethylation chemistry.