Published in

Royal Society of Chemistry, Chemical Science, 43(10), p. 10072-10078, 2019

DOI: 10.1039/c9sc02467k

Links

Tools

Export citation

Search in Google Scholar

Caesium fluoride-mediated hydrocarboxylation of alkenes and allenes: scope and mechanistic insights

Journal article published in 2019 by Ashot Gevorgyan ORCID, Marc F. Obst ORCID, Yngve Guttormsen, Feliu Maseras ORCID, Kathrin H. Hopmann ORCID, Annette Bayer ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

Full text: Download

Red circle
Preprint: archiving forbidden
Green circle
Postprint: archiving allowed
Upload
Green circle
Published version: archiving allowed
Upload
Policy details
Data provided by SHERPA/RoMEO

Abstract

A caesium fluoride-mediated regioselective hydrocarboxylation of alkenes and allenes is described. Computational studies reveal that the stability of an organocaesium intermediate accounts for the observed reactivity.