Published in
Royal Society of Chemistry, Chemical Science, 43(10), p. 10003-10009, 2019
DOI: 10.1039/c9sc03694f
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Chiroptical inversion of a planar chiral redox-switchable rotaxane
Journal article published in 2019 by
Marius Gaedke,
Felix Witte,
Jana Anhäuser,
Henrik Hupatz,
Hendrik V. Schröder 
,
Arto Valkonen ,
Kari Rissanen ,
Arne Lützen ,
Beate Paulus,
Christoph A. Schalley
,
Arto Valkonen ,
Kari Rissanen ,
Arne Lützen ,
Beate Paulus,
Christoph A. Schalley
This paper is made freely available by the publisher.
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Abstract
Reversible redox-switching of a planar chiral [2]rotaxane with a tetrathiafulvalene-bearing crown ether macrocycle generates a complete sign reversal of the main band in the ECD spectrum, as shown by experiment and rationalised by DFT calculations.