Abstract In this work we study the electronic structure of Ag 3 AuSe 2 and Ag 3 AuTe 2 , two chiral insulators whose gap can be tuned through small changes in the lattice parameter by applying hydrostatic pressure or choosing different growth protocols. Based on first principles calculations we compute their band structure for different values of the lattice parameters and show that while Ag 3 AuSe 2 retains its direct narrow gap at the Γ point, Ag 3 AuTe 2 can turn into a metal. Focusing on Ag 3 AuSe 2 we derive a low energy model around Γ using group theory, which we use to calculate the optical conductivity for different values of the lattice constant. We discuss our results in the context of detection of light dark matter particles, which have masses of the order of a keV, and conclude that Ag 3 AuSe 2 satisfies three important requirements for a suitable detector: small Fermi velocities, meV band gap, and low photon screening. Our work motivates the growth of high-quality and large samples of Ag 3 AuSe 2 to be used as target materials in dark matter detectors.