Published in
Royal Society of Chemistry, Chemical Science, 39(10), p. 9115-9124, 2019
DOI: 10.1039/c9sc02357g
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Supramolecular interactions between catalytic species allow rational control over reaction kinetics
Journal article published in 2019 by
Abraham J. P. Teunissen 
,
Tim F. E. Paffen,
Ivo A. W. Filot,
Menno D. Lanting,
Roy J. C. van der Haas,
Tom F. A. de Greef ,
E. W. Meijer
,
Tim F. E. Paffen,
Ivo A. W. Filot,
Menno D. Lanting,
Roy J. C. van der Haas,
Tom F. A. de Greef ,
E. W. Meijer
This paper is made freely available by the publisher.
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Abstract
The non-covalent interactions between two phase-transfer catalysts allow tuning of reaction kinetics from bimolecular, to pseudo 0th order, to sigmoidal. Kinetic models and DFT calculations are used to obtain detailed insight in the system.