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Wiley, Angewandte Chemie, 2(125), p. 596-599, 2012

DOI: 10.1002/ange.201208554

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A generic one-pot route to acyclic two-coordinate silylenes from silicon(IV) precursors: synthesis and structural characterization of a silylsilylene.

Journal article published in 2012 by Av Protchenko, Ad Schwarz, Matthew P. Blake, Cameron Jones, Nikolas Kaltsoyannis ORCID, Philip Mountford, Simon Aldridge
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Si in sight: a one-pot, single-step synthesis of an acyclic silylsilylene, Si{Si(SiMe(3))(3)}{N(SiMe(3))Dipp} (Dipp=2,6-iPr(2)C(6)H(3)), from a silicon(IV) starting material is reported, together with evidence for a mechanism involving alkali metal silylenoid intermediates.