EPL Association, European Physical Society Letters, 4(62), p. 588-594
DOI: 10.1209/epl/i2003-00391-2
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The combination of two techniques (Small Angle X-ray Scattering and Atomic Force Microscopy) has allowed us to measure in reciprocal and real space the correlation length $ξ$ of salt-free aqueous solutions of highly charged hydrophobic polyelectrolyte as a function of the polymer concentration $C_p$, charge fraction $f$ and chain length $N$. Contrary to the classical behaviour of hydrophilic polyelectrolytes in the strong coupling limit, $ξ$ is strongly dependent on $f$. In particular a continuous transition has been observed from $ξ ∼ C_p^{-1/2}$ to $ξ∼ C_p^{-1/3}$ when $f$ decreased from 100% to 35%. We interpret this unusual behaviour as the consequence of the two features characterising the hydrophobic polyelectrolytes: the pearl necklace conformation of the chains and the anomalously strong reduction of the effective charge fraction. ; Comment: 7 pages, 5 figures, submitted to Europhysics Letters