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Wiley, Advanced Synthesis & Catalysis, 2-3(356), p. 437-446, 2014

DOI: 10.1002/adsc.201300703

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Expanding the scope of the organocatalytic addition of Fluorobis(phenylsulfonyl)methane to Enals: enantioselective cascade synthesis of Fluoroindane and Fluorochromanol derivatives

Journal article published in 2014 by Young Sug Kim, Sun Min Kim, Bing Wang, Xavier Companyó ORCID, Jing Li, Albert Moyano, Seoyoung Im, Zdeněk Tošner, Jung Woon Yang, Ramon Rios
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Highly enantioselective cascade reactions for the synthesis of fluoroindanes and chromanols derivatives are described. The cascade reactions consisted of either a double Michael reaction or Michael–hemiacetal formation via the addition of fluorobis(phenylsulfonyl)methane (FBSM) to enals. The final products were obtained in good yields with excellent stereoselectivities.