Published in
Royal Society of Chemistry, RSC Advances, 44(9), p. 25776-25789, 2019
DOI: 10.1039/c9ra05334d
Links
Tools
How intramolecular coordination bonding (ICB) controls the homolysis of the C–ON bond in alkoxyamines
Journal article published in 2019 by
Gérard Audran,
Elena Bagryanskaya 
,
Irina Bagryanskaya,
Mariya Edeleva ,
Jean-Patrick Joly,
Sylvain R. A. Marque ,
Anna Iurchenkova,
Polina Kaletina,
Sergey Cherkasov,
Tung To Hai,
Evgeny Tretyakov ,
Svetlana Zhivetyeva
,
Irina Bagryanskaya,
Mariya Edeleva ,
Jean-Patrick Joly,
Sylvain R. A. Marque ,
Anna Iurchenkova,
Polina Kaletina,
Sergey Cherkasov,
Tung To Hai,
Evgeny Tretyakov ,
Svetlana Zhivetyeva
This paper is made freely available by the publisher.
Full text: Download
Preprint: archiving forbidden
Data provided by 
Abstract
Because the C–ON bond homolysis rate constant kd is an essential parameter of alkoxyamine reactivity, it is especially important to tune kd without a major alteration of the structure of the molecule.