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Royal Society of Chemistry, Chemical Science, 32(10), p. 7561-7573, 2019

DOI: 10.1039/c8sc05598j

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Using sulfur bridge oxidation to control electronic coupling and photochemistry in covalent anthracene dimers

Journal article published in 2019 by Chad D. Cruz, Jennifer Yuan ORCID, Clàudia Climent ORCID, Nathan T. Tierce, Peter R. Christensen ORCID, Eric L. Chronister, David Casanova ORCID, Michael O. Wolf ORCID, Christopher J. Bardeen ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

For anthracene dimers bridged by a sulfur atom, modulating the sulfur oxidation state profoundly affects excited state behavior. The SO2-bridge supports long-lived states and photodimerization, while the S-bridge undergoes intersystem crossing.