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American Chemical Society, Journal of Organic Chemistry, 14(72), p. 5025-5034, 2007

DOI: 10.1021/jo061878x

Wiley-VCH Verlag, ChemInform, 48(38), 2007

DOI: 10.1002/chin.200748206

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Arenicolides A−C, 26-Membered Ring Macrolides from the Marine ActinomyceteSalinispora arenicola

Journal article published in 2007 by Philip G. Williams, Eric D. Miller, Ratnakar N. Asolkar, Paul R. Jensen, William Fenical ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Chemical evaluation of the saline fermentation broth of several strains of the obligate marine actinomycete Salinispora arenicola has led to the identification of three new macrolide polyketides designated arenicolides A-C( 1–3). The planar structures, elucidated via spectroscopic and chemical methods, consist of 26-membered polyunsaturated macrolactones containing repeating vicinal hydroxyl methoxyl moieties. The relative and absolute stereochemistries of 1–3 were assigned by a combination of J-based configurational analyses and chemical derivatization.