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Royal Society of Chemistry, Chemical Science, 28(10), p. 6868-6875, 2019

DOI: 10.1039/c9sc01701a

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Formation of an imidazoliumyl-substituted [(LC)4P4]4+ tetracation and transition metal mediated fragmentation and insertion reaction (LC = NHC)

Journal article published in 2019 by Kai Schwedtmann, Jan Haberstroh, Sven Roediger, Antonio Bauzá ORCID, Antonio Frontera ORCID, Felix Hennersdorf ORCID, Jan J. Weigand ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Tetracationic cyclo-tetraphosphane [(LC)4P4]4+as triflate salt (LC= 4,5-dimethyl-1,3-diisopropyl-imidazol-2-yl) is obtained from the reduction of [LCPCl2]+with 1,4-bis(trimethylsilyl)-1,4-dihydropyrazine and represents the first salt of the cationic cyclo-phosphane series with the general formula [LnPn]n+.