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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 8(68), p. m1026-m1026, 2012

DOI: 10.1107/s1600536812029364

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trans-Bis(nitrato-κO)bis(1,10-phenanthroline-κ2N,N′)manganese(II)

Journal article published in 2012 by Watcharin Saphu, Songwuit Chanthee, Kittipong Chainok, David J. Harding ORCID, Chaveng Pakawatchai
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In the title compound, [Mn(NO3)2(C12H8N2)2], the MnIIatom lies on a twofold rotation axis, and is six-coordinated in a distortedtrans-N4O2octahedral environment by four N atoms from two 1,10-phenanthroline ligands and two O atoms from two nitrate anions. The nitrate anion is disordered about a twofold rotation axis with fixed occupancy factors of 0.5. In the crystal, molecules are linked by weak C—H...O hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 4.088 (5) Å] into a three-dimensional supramolecular network.