Elsevier, Materials Science and Engineering: B, 1-3(144), p. 43-48
DOI: 10.1016/j.mseb.2007.07.102
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We report here on the growth of NiFe2O4 epitaxial thin films of different thickness (3 nm <= t <= 32 nm) on single crystalline substrates having spinel (MgAl2O4) or perovskite (SrTiO3) structure. Ultrathin films, grown on any of those substrates, display a huge enhancement of the saturation magnetization: we will show that partial cationic inversion may account for this enhancement, although we will argue that suppression of antiparallel collinear spin alignment due to size-effects cannot be excluded. Besides, for thicker films, the magnetization of films on MAO is found to be similar to that of bulk fertile; in contrast, the magnetization of films on STO is substantially lower than bulk. We discuss on the possible mechanisms leading to this remarkable difference of magnetization. (C) 2007 Elsevier B.V. All rights reserved.