The stability of the photovoltaic (PV) modules is critical when deployed in a non-ideal environment. Among the different factors, temperature and humidity are the two major factors affecting PV stability, making them significant causes of its degradation in terms of optoelectric and materials properties. Nowadays, with the increase in PV installation (here, we are only taking account of c-Si-based PV modules) to generate green electricity, effective space utilization is an important issue. Recently, people have been considering deploying PV modules on the road to utilize the space available on highways (roadways). This raises several new issues in the deployment of PV modules. However, issues related to temperature and humidity retain the same importance. Normally, these stability tests are performed in a damp-heat (DH) stress-testing chamber in an accelerated condition at 85 °C and 85% relative humidity (RH). In this work, c-Si PV modules were fixed over a concrete slab to prepare a PV interacted block, which can be used to build concrete-based roads. The performance of this PV on the concrete slab was tested in a DH stress-testing chamber in an accelerated condition at 85 °C and 85% RH for 4000 h. For the comparison, a PV module without concrete was also evaluated. The degradation of the PV modules was characterized using the electroluminescence scanning technique. After 2500 h of exposure to the DH conditions, the performance retention of the PV modules mounted on the concrete was 93.2%, which was nearly 5% higher than the module without the concrete slab.