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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 4(70), p. m131-m132, 2014

DOI: 10.1107/s1600536814003894

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Di­chlorido­[N-(N,N-di­methyl­carbamimido­yl)-N′,N′,4-tri­methyl­benzohydrazonamide]­platinum(II) nitro­methane hemisolvate

Journal article published in 2014 by Dmitrii S. Bolotin ORCID, Nadezha A. Bokach ORCID, Matti Haukka
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In the title compound, [PtCl2(C13H21N5)]·0.5CH3NO2, the PtIIatom is coordinated in a slightly distorted square-planar geometry by two Cl atoms and two N atoms of the bidentate ligand. The (1,3,5-triazapentadiene)PtIImetalla ring is slightly bent and does not conjugate with the aromatic ring. In the crystal, N—H...Cl hydrogen bonds link the complex molecules, forming chains along [001]. The nitromethane solvent molecule shows half-occupancy and is disordered over two sets of sites about an inversion centre.