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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 2(70), p. m58-m59, 2014

DOI: 10.1107/s1600536814000907

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Tetrakis[bis(pyridin-2-yl)amine-κN2](nitrato-κO)silver(I)

Journal article published in 2014 by Yuliia Parashchenko, Anna Pavlishchuk, Nadezhda A. Bokach ORCID, Matti Haukka
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In the title complex, [Ag(NO3)(C10H9N3)4], the nitrate ligand is found to be disordered over two sets of positions, with occupancy factors of 0.473 (5) and 0.527 (5). The AgIion is located in a square-pyramidal coordination environment formed by four N atoms from four bis(pyridin-2-yl)amine ligands and one O atom from a nitrate ligand. Weak interactions between the AgIions and the nitrate anions acting in a monodentate mode [Ag...O = 2.791 (13) and 2.816 (9) Å for the major component of the nitrate ligand, and 2.865 (8) and 2.837 (8) Å for the minor component] link the complex molecules into a chain along [001]. N—H...O hydrogen bonds are observed.