Published in
Royal Society of Chemistry, Chemical Science, 15(10), p. 4313-4321, 2019
DOI: 10.1039/c8sc05218b
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De novo synthesis of mesoporous photoactive titanium(iv)–organic frameworks with MIL-100 topology
Journal article published in 2019 by
Javier Castells-Gil 
,
Natalia M. Padial ,
Neyvis Almora-Barrios ,
Ivan da Silva ,
Diego Mateo,
Josep Albero,
Hermenegildo García ,
Carlos Martí-Gastaldo
,
Natalia M. Padial ,
Neyvis Almora-Barrios ,
Ivan da Silva ,
Diego Mateo,
Josep Albero,
Hermenegildo García ,
Carlos Martí-Gastaldo
This paper is made freely available by the publisher.
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Abstract
The development of new titanium frameworks remains limited by the difficulties in forming persistent Ti clusters amenable to the isoreticular approach. MIL-100(Ti) combines a mesoporous structure with excellent chemical stability and photoactivity from the reticulation of Ti3(μ3-O) metal-oxo clusters.