International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 7(68), p. o1999-o2000, 2012
DOI: 10.1107/s1600536812024294
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The title compound, C21H19ClN2OS, exists in a cis conformation with respect to the N=C bond [1.2608 (13) Å]. The cyclohexene ring adopts a distorted half-chair conformation. The thiazolidine ring is close to being planar (r.m.s. deviation = 0.057 Å) and makes dihedral angles of 62.92 (6) and 56.32 (6)°, respectively, with the benzene ring and the chloro-substituted benzene ring. The dihedral angle between the benzene ring and the chloro-substituted benzene ring is 72.91 (6)°. In the crystal, molecules are linked by C—H⋯O and C—H⋯N hydrogen bonds into undulating sheets lying parallel to the bc plane. The crystal is further consolidated by C—H⋯π interactions.