Published in
International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 7(68), p. o1994-o1994, 2012
DOI: 10.1107/s1600536812024646
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(Z)-3-(4-Bromophenyl)-2-[(2-phenylcyclohex-2-en-1-yl)imino]-1,3-thiazolidin-4-one
,
Ching Kheng Quah,
Murugan Sathishkumar,
Alagusundaram Ponnuswamy
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Abstract
The title compound, C(21)H(19)BrN(2)OS, exists in a cis conformation with respect to the N=C bond [1.2602 (14) Å]. The cyclo-hexene ring adopts a distorted half-chair conformation and the C-N bond lies in an equatorial orientation. The thia-zolidine ring forms dihedral angles of 53.76 (7) and 57.22 (7)° with the benzene and bromo-substituted benzene rings, respectively. The dihedral angle between the benzene and bromo-substituted benzene rings is 76.06 (7)°. In the crystal, inversion dimers linked by pairs of C-H⋯O hydrogen bonds generate R(2) (2)(14) loops. The crystal is further consolidated by weak C-H⋯π inter-actions.