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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 11(67), p. m1563-m1564, 2011

DOI: 10.1107/s1600536811041523

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Hexa­kis­(dimethyl­formamide-κO)manganese(II) μ-oxido-bis­[trichlorido­ferrate(III)]

Journal article published in 2011 by Eduard N. Chygorin, Svitlana R. Petrusenko, Volodymyr N. Kokozay ORCID, Yuri O. Smal, Irina V. Omelchenko ORCID, Oleg V. Shishkin
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The title compound, [Mn(C(3)H(7)NO)(6)][Fe(2)Cl(6)O], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes with Schiff base ligands using manganese powder and FeCl(3)·6H(2)O as starting materials. In the [Fe(2)OCl(6)](2-) anion, the O atom and the Fe atom occupy positions with site symmetry [Formula: see text] and 3, respectively, resulting in a linear Fe-O-Fe angle and a staggered conformation. The octa-hedrally surrounded cation (site symmetry [Formula: see text]) and the [Fe(2)Cl(6)O](2-) anion are alternately stacked along [001].