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Oxford University Press, Metallomics, 12(10), p. 1777-1791, 2018
DOI: 10.1039/c8mt00264a
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Non-coordinative metal selectivity bias in human metallothioneins metal–thiolate clusters
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Abstract
Mammalian metallothioneins MT-2 and MT-3 contain two metal–thiolate clusters through cysteine coordination of d10 metals, Cu(i) and Zn(ii), and isoform-specific non-coordinating residues control their respective zinc– and copper–thionein character.