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A Facile Synthesis of Pyrido[,:3,4]pyrazolo[1,5-a]pyrimidine and Pyrido[,:3,4]pyrazolo[5,1-c][1,2,4]triazine Bearing a Thiophene Moiety

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This paper is available in a repository.

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Abstract

Pyridinone derivative 8 was synthesized and transformed into the respective chloropyridine 9, which was allowed to react with hydrazine hydrate to afford pyrazolo[3,4-b]pyridin-3-amine derivative 11. Compound 11 was used as a key intermediate for a facile synthesis of the title compounds 14, 15, 17, 21a,b, and 24a–c where the reaction of 11 with some 1,3-dielecrophiles resulted in the formation of pyrido[2`,3`:3,4] pyrazolo[1,5-a]pyrimidines 14, 15, and 17, whereas diazotization of compound 11 gave the respective diazonium salt 18 which was coupled with some active methylene-containing compounds to give the corresponding hydrazones 19a,b and 22a–c. Cyclization of the latter hydrazones yielded the pyrido[2`,3`:3,4]pyrazolo[5,1-c][1,2,4]triazines 21a,b and 24a–c, respectively