International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 5(68), p. o1510-o1511, 2012
DOI: 10.1107/s1600536812017114
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In the title compound, C14H12BrClN4OS, the thienyl ring is disordered over two orientations with a site-occupancy ratio of 0.853 (2):0.147 (2). The molecule is roughly planar, with the dihedral angles between the thienyl and benzene rings being 6.24 (16) and 9.7 (11)° for the major and minor components, respectively. The central fragment is almost planar [r.m.s. deviation = 0.0275 (2) Å for the ten non-H atoms]. The mean plane through this middle unit makes a dihedral angle of 2.71 (7)° with the benzene ring, whereas these values are 4.46 (15) and 7.7 (11)° for the major and minor components of the thienyl ring, respectively. In the crystal, molecules are linked into dimers by pairs of N—H⋯O hydrogen bonds, forming R 2 2(8) ring motifs. These dimers are arranged into sheets parallel to the ac plane.