Published in

International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 5(68), p. o1438-o1438, 2012

DOI: 10.1107/s1600536812015358

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4-Benzyl-8-phenyl-1-thia-4-aza­spiro­[4.5]decan-3-one

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In the title compound, C(21)H(23)NOS, the thia-zolidine ring adopts a twist conformation about one of its C-S bonds, while the cyclo-hexane ring has a chair conformation. The S and N atoms attached to the spiro C atom are in axial and equatorial orientations, respectively. The thia-zolidine ring forms dihedral angles of 86.24 (14) and 31.82 (15)° with the directly attached and remote terminal benzene rings, respectively. The dihedral angle between the two terminal benzene rings is 86.74 (14)°. In the crystal, the only significant directional inter-action is a weak C-H⋯π bond, which generates [010] chains.