Published in

American Association for the Advancement of Science, Science, 6354(357), p. 898-903, 2017

DOI: 10.1126/science.aan5630

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Dynamic multinuclear sites formed by mobilized copper ions in NO x selective catalytic reduction

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

X-ray vision spies copper on the move Copper ions in zeolites help remove noxious nitrogen oxides from diesel exhaust by catalyzing their reaction with ammonia and oxygen. Paolucci et al. found that these copper ions may move about during the reaction (see the Perspective by Janssens and Vennestrom). Zeolite catalysts generally fix metals in place while the reacting partners flow in and out of their cagelike structures. In this case, though, x-ray absorption spectroscopy suggested that the ammonia was mobilizing the copper ions to pair up as they activated oxygen during the catalytic cycle. Science , this issue p. 898 ; see also p. 866