Dissemin is shutting down on January 1st, 2025

Published in

American Association for the Advancement of Science, Science, 6375(359), p. 572-575, 2018

DOI: 10.1126/science.aar2287

Links

Tools

Export citation

Search in Google Scholar

Polarity compensation mechanisms on the perovskite surface KTaO3(001)

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Green circle
Preprint: archiving allowed
Green circle
Postprint: archiving allowed
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

Compensating a polar surface An ionic crystal surface can be electrostatically unstable, and the surface must reconstruct in some way to avoid this “polar catastrophe.” Setvin et al. used scanning probe microscopies and density functional theory to study the changes in the polar surface of the perovskite KTaO 3 . They observed several structural reconstructions as the surface cleaved in vacuum was heated to higher temperatures. These ranged from surface distortions to the formation of oxygen vacancies to the development of KO and TaO 2 stripes. Hydroxylation after exposure to water vapor also stabilized the surface. Science , this issue p. 572