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Wiley, Advanced Materials, 17(24), p. 2357-2361, 2012

DOI: 10.1002/adma.201200751

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Porous, Fluorescent, Covalent Triazine-Based Frameworks Via Room-Temperature and Microwave-Assisted Synthesis

Journal article published in 2012 by Shijie Ren, Michael J. Bojdys, Robert Dawson, Andrea Laybourn, Yaroslav Z. Khimyak, Dave J. Adams ORCID, Andrew I. Cooper
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Porous, fluorescent, covalent triazine-based frameworks (CTFs) are obtained in an unprecedentedly mild reaction, opening up a scalable pathway for molecular building blocks previously thought incompatible with this chemistry. Choice of monomers and synthetic conditions determines the optical properties and nano-scale ordering of these highly microporous materials with BET surface areas exceeding 1100 m(2) g(-1) and exceptional CO(2) capacities (up to 4.17 mmol g(-1)).