Published in

National Academy of Sciences, Proceedings of the National Academy of Sciences, 51(114), p. 13380-13384, 2017

DOI: 10.1073/pnas.1711836114

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Self-healing catalysis in water

Journal article published in 2017 by Cyrille Costentin ORCID, Daniel G. Nocera ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Significance Water provides an attractive medium for storing solar energy via water splitting. Charge-separated states generated by solar capture may be transferred to catalysts that split water to hydrogen and oxygen. Most water-splitting catalysts comprising earth-abundant elements are susceptible to corrosion when operated in neutral and natural water. Such corrosion may be circumvented if the catalysts are self-healing. The design of self-healing catalysts allows neutral water and natural water sources to be used for water splitting, greatly simplifying the implementation of using water as a distributed energy storage medium for solar energy.