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American Physical Society, Physical review B, 14(80), 2009

DOI: 10.1103/physrevb.80.140101

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Phenomenological analysis of domain width in rhombohedral BiFeO 3 films

Journal article published in 2009 by C. W. Huang, Lang Chen, J. Wang ORCID, Q. He, S. Y. Yang, Y. H. Chu ORCID, R. Ramesh
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The experimental domain size scaling law in epitaxial BiFeO3 films shows a different behavior from predictions of the conventional elastic domains: the (101)-type 71° domains are much wider than that of (100)- type 109° despite the larger domain-wall energy in (100) boundary. A phenomenological analysis for rhombohedral BiFeO3 film is proposed, and it reveals that both the depolarizing energy and the elastic energy are indispensable for the equilibrium domain structures. With the increase in the asymmetrical electrostatic boundary on the film surfaces, the dominant domain scaling mechanism changes from electrostatic-dependent domain structure to elastic-dependent one, which is consistent with the experimental data. The present results highlight the general role of depolarizing field in rhombohedral domain structures.