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International Union of Crystallography, IUCrData, 11(2), 2017

DOI: 10.1107/s2414314617016340

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2,6-[Bis(dimethylamino)methyl]phenylselenenyl chloride/bromide monohydrate

Journal article published in 2017 by Anand Gupta, Harkesh B. Singh, Ray J. Butcher ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In the title hydrated salt, C12H19N2Se+·Cl0.44/Br0.56−·H2O, the halide ions (both with site symmetry 2) have different Cl−/Br−occupancies of 0.399 (2)/0.601 (2) and 0.491 (2)/0.509 (2). In the crystal, the cation and anion are linked by an Se...X(X= Cl/Br) interaction of length 3.5593 (8) Å. The water molecule and anions are linked by O—H...Xhydrogen bonds into a staggered chain propagating in theb-axis direction and the packing is consolidated by weak C—H...Xinteractions.