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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 6(62), p. m1373-m1375, 2006

DOI: 10.1107/s1600536806016679

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Poly[methylamine-mu-oxalato-copper(II)]

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The six-coordinate copper(II) ions in the title compound, [Cu(C2O4)(CH5N)], experience a Jahn-Teller distortion. The structure is a two-dimensional coordination network, with three crystallographically independent oxalate ions, two of them centrosymmetric, bridging Cu-II ions in three different coordination modes. Each Cu ion is also coordinated by methyl-amine which is involved in both intra- and inter-layer hydrogen bonding.