Published in

American Association for the Advancement of Science, Science, 6361(358), p. 352-355, 2017

DOI: 10.1126/science.aan6837

Links

Tools

Export citation

Search in Google Scholar

Single polymer growth dynamics

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Green circle
Preprint: archiving allowed
Green circle
Postprint: archiving allowed
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

Watching growth, step by step Polymers can grow through the stepwise addition of monomers to an active end site. One might think that this would happen in a continuous linear process. With a focus on ring-opening metathesis polymerization of norbornene catalyzed by a Grubbs' catalyst, Liu et al. describe the growth of a single polymer chain. By attaching one end of a growing polymer to a bead exerting a constant force on it, they measured the extension occurring during the growth of the polymer. Oddly, the extension of the growing polymer did not increase continuously. Instead, it exhibited consecutive wait-and-jump steps, owing to conformational entanglements formed by newly incorporated monomers. Science , this issue p. 352