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Thieme Gruppe, Synlett: Accounts and Rapid Communications in Synthetic Organic Chemistry, 20(27), p. 2799-2802, 2016

DOI: 10.1055/s-0036-1588312

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Synthesis of Polyhydroxylated Conidine Alkaloid as a Conformationally Restricted Azasugar

Journal article published in 2016 by Shrinivas G. Dumbre ORCID, Sujit Pal
Distributing this paper is prohibited by the publisher
Distributing this paper is prohibited by the publisher

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Abstract

A conformationally restricted polyhydroxylated 1-azabicy­clo[4.2.0]octane core has been synthesized in search for a potent selective glycosidase inhibitor. The key feature of the synthesis involves the high stereoselective photoelectron-transfer-promoted cyclization of the strained α-trimethylsilylmethylazetidine moiety to the tethered π functionality.